Colorado State University NSF-REU Summer Program in Materials Chemistry Research:

Synthesis, Characterization, and Device Fabrication

Ellen R. Fisher

For more information, visit our group webpage…

A major focus of Fisher group research is exploring the chemistry of low temperature plasmas used to deposit thin film materials or nanostructured materials. Plasma enhanced chemical vapor deposition, surface modification, and polymerization are used in several fields including the biomedical and semiconductor industries as well as for production or modification of materials used in renewable energy devices.  REU projects have concentrated on plasma polymerization of organic thin films, modification of porous polymeric materials, and production of metal oxide films for energy-related applications.  Two project goals are to explore the gas-phase chemistry of the plasma as a function of process parameters and to produce films with particular properties (i.e., good biocompatability, energy conversion, or high wettability).  Students characterize film properties using analytical tools including FTIR spectroscopy, and surface analysis techniques.  Students also utilize gas-phase diagnostics to explore plasma chemistry.  Film composition is explored by varying plasma conditions such as applied rf power, plasma pressure, starting materials, and substrate temperature.  A recent REU project focused on creating patterned surfaces using two sequential plasma treatments to create a grid of alternating hydrophobic (fluorocarbon) and hydrophilic (poly acrylic acid) areas.  Another project focused on modifying hydrophobic polymeric membranes to create hydrophilic surfaces using H2O2 plasmas.  The REU student also tested modified materials for protein fouling using model protein solutions, finding that the membranes had lower fouling and were easier to clean.

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